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Hindered amine light stabilizers



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Hindered amine light stabilizers (HALS) are chemical compounds containing an amine functional group that are used as stabilizers in plastics and polymers.These compounds are typically derivatives of tetramethylpiperidine and are primarily used to protect the polymers from the effects of photo-oxidation; as opposed to other forms of polymer degradation such as ozonolysis. They are also increasingly being used as thermal stabilizers,particularly for low and moderate level of heat, however during the high temperature processing of polymers (e.g. injection moulding) they remain less effective than traditional phenolic antioxidants.

Mechanism of action


HALS do not absorb UV radiation, but act to inhibit degradation of the polymer by continuously and cyclically removing free radicals that are produced by photo-oxidation of the polymer.Partial structure of a typical hindered amine light stabilizerThe overall process is sometimes referred to as the Denisov cycle, after Evguenii T. Denisov and is exceedingly complex.Broadly, HALS react with the initial polymer peroxy radical (ROO?) and alkyl polymer radicals (R?) formed by the reaction of the polymer and oxygen, preventing further radical oxidation. By these reactions HALS are oxidised to their corresponding aminoxyl radicals (R2NO? c.f. TEMPO), however they are able to return to their initial amine form via a series of additional radical reactions. HALS's high efficiency and longevity are due to this cyclic process wherein the HALS are regenerated rather than consumed during the stabilization process.

Initial reaction of a HAL with a polymer peroxy radical: this step stabilizes the polymer and converts the HAL to its aminoxyl form.

Application



Even though HALS are extremely effective in polyolefins, polyethylene and polyurethane, they are ineffective in polyvinyl chloride (PVC). It is thought that their ability to form nitroxyl radicals is disrupted due them being readily protonated by HCl released by dehydrohalogenation of PVC.


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